First woman in D.U. HOF--Beth Hochrein (6'2")-26 PPG- HOF WBB --could play any position 1 through 5--and Tennis---#3 seed on men's team. Doubles partner Liz Stockhausen (8-2 vs. male opponents)   D.U's first really, really good female athlete. Eileen Livingston and Sam Hazo were her coaches.  Legend and lore has it that she beat Willie Somerset in one-on-one game at old gym. I wasn't there.  I don't doubt it!  I  crafted and wrote the sports section of the L'Esprit Du Duc in '65. Saw her often. 

I'd add as bench players Kelly Eberhart from North Catholic, Sherri Hannon- from the North Hills and the shooting guards from Char Valley and Monaca, whose names escape me, ( one of them used to tend bar at Shale's-- Sarge Brown's favorite player!!) 

1963 through 1966 inclusive.  The then Duchesses were the first team to use the full court as did the men's teams.  You might be able to archive the L'Esprit Du Duc issues for 1965 and 1966. Let me correct something.  Phyllis Sanguini was the Duchesses coach, not Eileen Livingston.